Green chemistry yakula kwambiri m'zaka zaposachedwa chifukwa choyang'ana kwambiri machitidwe okhazikika komanso okonda zachilengedwe.Dera limodzi lomwe lawona kupita patsogolo kwakukulu ndikukula ndi kugwiritsa ntchito zida zothandizira zomwe zingalimbikitse kuyanjanitsa kwachilengedwe.Tetrabutylammonium iodide (TBAI) yatuluka ngati imodzi mwazothandizira, ndi mawonekedwe ake apadera akupangitsa kuti ikhale yoyenera kulimbikitsa kusintha kwa chemistry yobiriwira.
TBAI, ndi nambala ya CAS 311-28-4, ndi mchere wa quaternary ammonium wopangidwa ndi tetraalkylammonium cation ndi anion iodide.Ndi woyera crystalline olimba kuti kwambiri sungunuka mu wamba organic solvents.TBAI yaphunziridwa mozama ndikugwiritsidwa ntchito ngati chothandizira pazochitika zosiyanasiyana zamoyo, kuwonetsa mphamvu zake komanso kusinthasintha polimbikitsa chemistry yobiriwira.
Ubwino umodzi wogwiritsa ntchito TBAI ndikutha kufulumizitsa zomwe zimachitika ndikuchepetsa kufunikira kwazovuta.Traditional organic synthesis nthawi zambiri amafuna kutentha kwambiri ndi mavuto, komanso ntchito poizoni ndi woopsa reagents.Mikhalidwe imeneyi sikuti imangokhala yowopsa kwa chilengedwe komanso imayambitsa kutulutsa zinyalala zambiri.
Mosiyana ndi izi, TBAI imathandizira kuti machitidwe aziyenda bwino pakanthawi kochepa, kuchepetsa kugwiritsa ntchito mphamvu ndikuchepetsa kuwononga zinyalala.Izi ndizopindulitsa makamaka pazantchito zamafakitale, pomwe kukhazikitsidwa kwa mfundo zobiriwira za chemistry kumatha kubweretsa kupulumutsa kwakukulu komanso kupindulitsa chilengedwe.
TBAI yagwiritsidwa ntchito bwino pamasinthidwe osiyanasiyana obiriwira obiriwira.Zakhala zikugwiritsidwa ntchito ngati chothandizira pakuphatikizika kwazinthu zosiyanasiyana zachilengedwe, kuphatikiza mankhwala apakatikati ndi mankhwala abwino.Kuphatikiza apo, TBAI yawonetsa lonjezo lalikulu polimbikitsa njira zokondera zachilengedwe monga kusandulika kwa biomass kukhala ma biofuel ofunikira komanso ma oxidation osankhidwa a organic substrates.
The wapadera katundu waTBAIzomwe zimapangitsa kuti ikhale yothandiza kwambiri pakusintha kwa chemistry yobiriwira ndikutha kwake kuchita ngati chothandizira kutengerapo gawo komanso gwero la ayodini a nucleophilic.Monga chothandizira kutengerapo gawo, TBAI imathandizira kusamutsa ma reactants pakati pa magawo osiyanasiyana, kukulitsa momwe amachitira komanso kulimbikitsa mapangidwe omwe akufuna.Mawonekedwe ake a nucleophilic iodide amalola kuti azitha kutenga nawo gawo pazosintha zosiyanasiyana ndikuwonjezera, kuyambitsa maatomu a ayodini m'mamolekyu achilengedwe.
Kuphatikiza apo, TBAI imatha kubwezeretsedwanso ndikusinthidwanso, ndikupititsa patsogolo kukhazikika kwake.Pambuyo pomaliza, TBAI ikhoza kulekanitsidwa ndi kusakaniza komwe kunachitika ndikugwiritsiridwanso ntchito pakusintha kotsatira, kuchepetsa ndalama zonse zomwe zimathandizira komanso kuchepetsa mavuto otaya zinyalala.
Kugwiritsiridwa ntchito kwa TBAI monga chothandizira kusintha kwa chemistry yobiriwira ndi chitsanzo chimodzi chabe cha momwe ofufuza ndi akatswiri amakampani akugwira ntchito mosalekeza kuti apange njira zokhazikika.Pogwiritsa ntchito zopangira zomwe zili zogwira mtima, zogwira mtima, komanso zokonda zachilengedwe, titha kuchepetsa kwambiri kukhudzidwa kwa chilengedwe ndi njira zamakina, kuzipangitsa kukhala zokhazikika komanso zokhazikika.
Pomaliza,Tetrabutylammonium iodide (TBAI)watuluka ngati chothandizira champhamvu pakusintha kosiyanasiyana kwa chemistry yobiriwira.Kutha kwake kufulumizitsa ziwonetsero, kulimbikitsa machitidwe okonda zachilengedwe, ndikubwezeredwa mosavuta ndikusinthidwanso kumapangitsa kukhala woyenera kulimbikitsa machitidwe okhazikika komanso okonda zachilengedwe.Pamene ofufuza ndi akatswiri amakampani akupitiliza kufufuza ndi kukhathamiritsa makina othandizira, titha kuyembekezera kuwona kupita patsogolo kwakukulu pazachilengedwe, kusintha momwe timayendera kaphatikizidwe ka organic ndikuchepetsa kuwononga chilengedwe.
Nthawi yotumiza: Jul-27-2023